Poly[[μ3-3-(3-pyridyl)acrylato-κ3N:O:O′][μ2-3-(3-pyridyl)acrylato-κ3O,O′:O][μ2-3-(3-pyridyl)acrylato-κ2O:O′)]gadolinium(III)]

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3

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Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 Complexes

The synthesis of SmCl3(THF)3 from SmCl3.6H2O is described. The reaction of SmCl3(THF)3 with NaBH4 in dry THF gave white microcrystalline tris (tetrahydroborato) tris (tetrahydrofuran) samarium (III), Sm(BH4)3(THF)3. The vibrational and magnetic properties of Sm(BH4)3...